インドール誘導体の合成

シアニン系の蛍光色素にはインドール骨格が含まれていて、新成化学では自主研究に関連して数多くのインドール化合物の合成実績があります。

市販のインドールから誘導するケース、インドール骨格の構築等、多数実績があります。

Fischer Indole Synthesis

弊社では最近、Cyanine系蛍光色素の合成に力を入れているため合成実績の多くはFischer法ですが他にも様々なアプローチの合成経験が多数あり、最適な方法を選択することでご希望の構造を合成できると考えております。

Bischler Indole Synthesis

Bishler-Mohlau Indole Synthesis

Nenitzescu 5-Hydrozyindole Synthesis



Hemetsberger-Knittel　Indole synthesis

Nenitzescu Indole Synthesis

Saegusa-Ito Indole Synthesis

Gassman Indole Synthesis

Hinsberg-Stolle　Indole-Oxindole Synthesis



Bartoli Indole Synthesis

Batcho-Leimgruber　Indole synthesis

Hegedus Indole synthesis



Mori-Ban Indole Synthesis

Reissert　Indole Synthesis

Walser Indole Synthesis

Madelung Indole Synthesis


 
SCHEM No. Structure Compound Name Price (JPY) Purity Stock(mg)
06396

AADIS7-PEG13-COOH

119,600/0.1mg>95%0.3
04720

Cy5(1-Hex-CONH-PEG13-COOtBu 8,8-diMe 1'-Me 8',8'-diMe)

72,400/0.2mg>90%1.5
06518

Cy5(1-Hex-COOH 5-SO3H 8,8-diMe 1'-Et 5'-SO3H 8'-Me 8'-PEG11-OMe

64,600/0.1mg>90%0
06069

TMSI-PEG10-OH

64,600/0.1mg>95%0.1
06068

TMSI-PEG10-OTrt

64,600/0.3mg>95%9.0
06295

TMSI-PEG8-OH

63,300/0.9mg>95%12.8
06516

Cy5(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG6-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>90%0
06432

1-(5-carboxypentyl)-2-[(E,3E)-3-[1-[2-(2-methoxyethoxy)ethyl]-3-methyl-5-sulfo-3-(3-sulfopropyl)indolin-2-ylidene]prop-1-enyl]-3-methyl-3-(3-sulfopropyl)indol-1-ium-5-sulfonate

64,600/0.1mg>95%0
06417

Cy7(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG6-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>95%0
06426

Cy7(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG5-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>95%0
06419

Cy5(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG5-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>90%0
06511

3-(5-carboxypentyl)-1-[2-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]ethyl]-2-[(1E,3E,5E)-5-[3-(2-methoxyethyl)-1-methyl-1-(3-sulfopropyl)benzo[e]indol-2-ylidene]penta-1,3-dienyl]-1-methyl-8-sulfo-benzo[e]indol-3-ium-6-sulfonate

64,600/0.1mg>90%0
06509

1-(5-carboxypentyl)-2-[(E,3Z)-3-[1-ethyl-3-[2-(2-methoxyethoxy)ethyl]-3-methyl-5-sulfo-indolin-2-ylidene]prop-1-enyl]-3-[2-(2-methoxyethoxy)ethyl]-3-methyl-indol-1-ium-5-sulfonate

64,600/0.1mg>95%0
06434

2-[(E,3Z)-3-[1,3-bis[2-(2-methoxyethoxy)ethyl]-3-methyl-5-sulfo-indolin-2-ylidene]prop-1-enyl]-1-[2-[2-(2-carboxyethoxy)ethoxy]ethyl]-3-[2-(2-methoxyethoxy)ethyl]-3-methyl-indol-1-ium-5-sulfonate

64,600/0.1mg>95%0
06433

Cy5(1-Hex-COOH 5-SO3H 8-Me 8-PEG4-OMe 1'-Et 5'-SO3H 8'-Me 8'-PEG3-OMe)

64,600/0.1mg>90%0
06422

Cy5(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG4-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>90%0
06293

TMSI-PEG4-Pr-COOH

63,300/0.9mg>95%0
06062

Cy7(1-PEG4-COOH 5-SO3H 8,8-diMe 1'-Me 5'-SO3H 8',8'-diMe)

96,000/0.1mg>95%0.1
06059

AADIS7-PEG4-COOMe

119,600/0.1mg>95%3.9
06009

Cy7(1-PEG4-COOMe 5-SO3H 8,8-diMe 1'-Me 5'-SO3H 8',8'-diMe)

96,000/0.1mg>95%0
05970

Cy7(1-HexCOOH 5-SO3H 8,8-diMe 1'-PEG4-OH 8',8'-diMe)

64,600/0.1mg>95%0
05948

TMSI-PEG4-OH

64,600/0.2mg>95%15.7
05075

AADIS7-PEG3-OAc

64,600/0.5mg>95%3.0
03545

TMSI-PEG4-COOMe

64,600/0.1mg>95%1.6
06512

3-(5-carboxypentyl)-1-[2-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]ethyl]-2-[(1E,3E,5E)-5-[3-(2-methoxyethyl)-1-methyl-1-(3-sulfopropyl)benzo[e]indol-2-ylidene]penta-1,3-dienyl]-1-methyl-8-sulfo-benzo[e]indol-3-ium-6-sulfonate

64,600/0.1mg>90%0
06431

Cy7(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG3-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>95%0
06430

Cy5(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG4-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>90%0
06425

Cy7(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG3-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>95%0
06423

Cy7(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG3-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>95%0
06421

1-(5-carboxypentyl)-2-[(E,3E)-3-[1-[2-[2-(2-methoxyethoxy)ethoxy]ethyl]-3-methyl-5-sulfo-3-(3-sulfopropyl)indolin-2-ylidene]prop-1-enyl]-3-methyl-3-(3-sulfopropyl)indol-1-ium-5-sulfonate

64,600/0.1mg>95%0
06420

(3R)-1-(5-carboxypentyl)-2-[(E,3E)-3-[(3S)-1-[2-[2-(2-methoxyethoxy)ethoxy]ethyl]-3-methyl-5-sulfo-3-(3-sulfopropyl)indolin-2-ylidene]prop-1-enyl]-3-methyl-3-(3-sulfopropyl)indol-1-ium-5-sulfonate

64,600/0.1mg>95%0
06061

Cy7(1-Hex-COOH 5-SO3H 8,8-diMe 1'-PEG3-OAc 5'-SO3H 8',8'-diMe)

96,000/0.1mg>95%0.1
05146

TMSI-PEG3-OH

64,600/0.1mg>95%89.4
06515

2-[(E,3E)-3-[3,3-dimethyl-5-sulfo-1-[2-[2-(4-sulfobutoxy)ethoxy]ethyl]indolin-2-ylidene]prop-1-enyl]-3,3-dimethyl-1-[2-[2-(4-sulfobutoxy)ethoxy]ethyl]indol-1-ium-5-sulfonate

64,600/0.1mg>95%0
06513

3-[2-[(1E,3E,5Z)-5-[3,3-dimethyl-5-sulfo-1-(3-sulfopropyl)indolin-2-ylidene]penta-1,3-dienyl]-3-[5-[2-(2-hydroxyethoxy)ethylamino]-5-oxo-pentyl]-3-methyl-5-sulfo-indol-1-ium-1-yl]propane-1-sulfonate

64,600/0.1mg>95%0
06510

Cy7(1-Pr-SO3H 5-SO3H 8-Me 8-Hex-CONH-PEG2-OMe 1'-Pr-SO3H 5'-SO3H 8',8'-diMe)

64,600/0.1mg>95%0
06440

Cy7(1-HexCOOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG2-OMe 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>95%0
06439

Cy5(1-Hex-COOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG2-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>90%0
06460

TMI-PEG1-COOtBu

64,600/10mg>95%272.0
06459

TMI-PEG1-COOEt

64,600/10mg>95%258.2
06523

Cy7(1-PEG4-COOH 5-SO3H 8,8-di-Me 1'-PEG4-COOH 5'-SO3H 8',8'-diMe)(4-Et-SO3H)

64,600/0.1mg>95%0
06522

Cy7(1-HexCOOH 5-SO3H 8-Me 8-Pr-SO3H 1'-PEG4-OMe 5'-SO3H 8'-Me 8'-Pr-SO3H)

64,600/0.1mg>95%0
06521

1-(5-carboxypentyl)-2-[(E,3E)-3-[1-[2-(2-methoxyethoxy)ethyl]-3-methyl-5-sulfo-3-(3-sulfopropyl)indolin-2-ylidene]prop-1-enyl]-3-methyl-3-(3-sulfopropyl)indol-1-ium-5-sulfonate

64,600/0.1mg>95%0
06520

Cy5(1-PEG4-Pr-COOH 5-SO3H 8-Me 8-PEG4-OMe 1'-PE4-OMe 5'-SO3H 8'-Me 8'-PEG4-OMe)

64,600/0.1mg>90%0
06519

Cy7(1-HexCOOH 5-SO3H 8-Me 8-PEG4-OMe 1'-Et 5'-SO3H 8'-Me 8'-PEG4-OMe)

64,600/0.1mg>95%0
06517

1-(4-aminobutyl)-2-[(1E,3E,5E)-5-[1-(5-carboxypentyl)-3,3-dimethyl-indolin-2-ylidene]penta-1,3-dienyl]-3,3-dimethyl-indol-1-ium-5-sulfonate

119,600/0.1mg>95%0
06514

1-ethyl-2-[(E,3E)-3-[1-[6-(2-hydroxyethoxy)-6-oxo-hexyl]-3,3-dimethyl-5-sulfo-indolin-2-ylidene]prop-1-enyl]-3,3-dimethyl-indol-1-ium-5-sulfonate

64,600/0.1mg>95%0
06446

3-[2-[2-[(2E)-2-[(E)-3-[3,3-dimethyl-1-[2-[2-(3-sulfopropoxy)ethoxy]ethyl]indol-1-ium-2-yl]prop-2-enylidene]-3,3-dimethyl-indolin-1-yl]ethoxy]ethoxy]propane-1-sulfonic acid

64,600/0.1mg>95%0
06438

Cy7(1-HexCOOH 8,8-diMe 1'-Me 8',8'-diMe)(3,5-Pr-cyclic)

119,600/0.1mg>95%0
06418

Cy7(1-PEG5-COOH 5-SO3H 8-Me 8-PEG4-OMe 1'-PEG4-OMe 5'-SO3H 8'-Me 8'-PEG4-OMe)

64,600/0.1mg>95%0
06416

1-(5-carboxypentyl)-2-[(E,3E)-3-[1-[2-(2-methoxyethoxy)ethyl]-3-methyl-5-sulfo-3-(3-sulfopropyl)indolin-2-ylidene]prop-1-enyl]-3-methyl-3-(3-sulfopropyl)indol-1-ium-5-sulfonate

64,600/0.1mg>95%0
06337

AADI7-Et-OH

63,300/0.9mg>95%399.4
06336

TMI-Et-OH

inquire>90%2,799.9
06297

AADIS5-Et-OAc

64,600/0.2mg>95%8.0
06296

Cy5(1-Hex-COOH 5-SO3H 8,8-diMe 1'-Pr-SO3H 5'-SO3H 8',8'-diMe)

96,000/0.1mg>90%0.9
06114

AADIS7-Et-SO3H

64,600/0.1mg>80%7.6
06035

TMSI-Et-SO3H

64,600/0.5mg>80%20.4
05969

AADIS5-Hex-COOH

63,300/0.9mg>95%1.0
05959

AADIS5-Me

64,600/0.2mg>95%9.3
05954

AADIS7-Hex-COOH

64,600/0.1mg>95%0.1
05945

TMSI-acetoxyacetic acid

64,600/0.1mg>95%5.3
05944

TMSI-Me

inquire>95%3.3
05941

AADIS5-HexCOOH

63,300/0.9mg>95%31.2
05364

AADIS5-Et-SO3H

96,000/0.1mg>95%2.4
05147

Sulfo Cy3-diamine

64,600/0.2mg>95%5.0
05142

TMSI-Et-OH

72,000/5mg>95%325.6
05141

TMSI-acetic acid

64,600/0.3mg>95%13.3
05132

TMSI-Et-NH2

64,600/5mg>95%22.7
05072

AADIS7-Me

64,600/0.3mg>95%1.7
04136

TMSI-Hex-COOH

inquire>90%740.6
03607

TMSI-K salt

inquire>90%6,570.9
02837

4-(4-methoxyphenyl)-2,3,3a,8b-tetrahydro-1H-cyclopenta[b]indole

64,000/0.2mg>80%750.0
02834

1,2,3,4-tetrahydrocyclopent[b] indole

inquire>80%1.0
01980

Cy3-halolinker

64,600/0.3mg>95%0.1


オキシインドールの合成も対応可能です。

SCHEM No. Structure Compound Name Price (JPY) Purity Stock(mg)
04937

3-Bromo-2,2-bis(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)propanol, O-triphenylmethyl

70,700/0.1mg>95%50.0
03390

Indigo

64,600/75mg>90%31.8

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